Nota de FísicaPublicado
Effect of Conformation on Spin Lattice Relation in Azide Methemoglobin
Eliane Wajnberg; G. Bemski
1988
Datos de la publicación
- Autores
- Eliane Wajnberg; G. Bemski
- Tipo
- Nota de Física
- Estado
- Publicado
- Fecha de publicación
- 1988
- Descripción
- Spin lattice relaxation of <math>Fe^{3+}\,\!</math> has been measured as a function of temperature in azide methemoglobin in natural and heat denaturated condition. Of the two spin states present (S=1/2, and S=5/2) the high spin state always follows an Orbach mechanism of relaxation with a characteristic energy dependent on the protein conformation. In the absence of thermal equilibrium of the two spin states, the S=1/2 state follows a Raman relaxation process whose exponent, n, is related to the conformation of the protein.
- Año
- 1988
- Número
- CBPF-NF-003/88
- Vínculo con tesis
- No
- Vínculo con beca
- No